Chemical behaviour of trimethylammonium N-methylides substituted with nitrogen-containing heteroaromatic rings. Rearrangement of N,N-dimethyl- (pyridylmethyl)ammonium, N,N-dimethyl-(1-methylpyrrolylmethyl)ammonium and N,N-dimethyl-(1-methylindolylmethyl)ammonium N-methylides

Yasuhiro Maeda, Naohiro Shirai, Yoshiro Sato

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

N,N-Dimethyl(pyridylmethyl)ammonium N-methylides 2, 6, 11, N,N-dimethyl(1-methylpyrrolyl-methyl)ammonium N-methylides 15, 20 and N,N-dimethyl(1-methylindolylmethyl)ammonium N-methylides 23, 28 were generated by fluoride ion-induced desilylation of the corresponding (trimethylsilyl) methylammonium salts 1,5,10,14,19,22 and 27, and the isomerization products of the ylides were investigated.

Original languageEnglish
Pages (from-to)393-398
Number of pages6
JournalJournal of the Chemical Society, Perkin Transactions 1
Issue number4
Publication statusPublished - 01-12-1994
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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