TY - JOUR
T1 - Cis-Bis[(3-aminopropyl)dimethylphosphine-κ2N,P] palladium(II) dichloride methanol solvate
AU - Suzuki, Takayoshi
AU - Hasegawa, Atsushi
AU - Yamaguchi, Hiroshi
AU - Kashiwabara, Kazuo
AU - Takagi, Hideo D.
PY - 2006/10
Y1 - 2006/10
N2 - In the title compound, CM-[Pd(C5Hi14NP) 2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P 2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 Å, indicating no obvious interaction.
AB - In the title compound, CM-[Pd(C5Hi14NP) 2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P 2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 Å, indicating no obvious interaction.
UR - http://www.scopus.com/inward/record.url?scp=33749485103&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33749485103&partnerID=8YFLogxK
U2 - 10.1107/S0108270106023596
DO - 10.1107/S0108270106023596
M3 - Article
AN - SCOPUS:33749485103
SN - 0108-2701
VL - 62
SP - m461-m463
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 10
ER -