Cis-Bis[(3-aminopropyl)dimethylphosphine-κ2N,P] palladium(II) dichloride methanol solvate

Takayoshi Suzuki; Atsushi Hasegawa; Hiroshi Yamaguchi; Kazuo Kashiwabara; Hideo D. Takagi

doi:10.1107/S0108270106023596

Cis-Bis[(3-aminopropyl)dimethylphosphine-κ²N,P] palladium(II) dichloride methanol solvate

Takayoshi Suzuki
, Atsushi Hasegawa
, Hiroshi Yamaguchi
, Kazuo Kashiwabara
, Hideo D. Takagi

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, CM-[Pd(C₅Hi₁₄NP) ₂]Cl₂·CH₄O, the coordination geometry around the Pd^II center is distorted square planar, with a cis-P ₂N₂ configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (C_s)-chair₂ conformer. The distances between the Pd^II center and the Cl^- anions are greater than 4.5 Å, indicating no obvious interaction.

Original language	English
Pages (from-to)	m461-m463
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	62
Issue number	10
DOIs	https://doi.org/10.1107/S0108270106023596
Publication status	Published - 10-2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Biochemistry,Genetics and Molecular Biology

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10.1107/S0108270106023596

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title = "Cis-Bis[(3-aminopropyl)dimethylphosphine-κ2N,P] palladium(II) dichloride methanol solvate",

abstract = "In the title compound, CM-[Pd(C5Hi14NP) 2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P 2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 {\AA}, indicating no obvious interaction.",

author = "Takayoshi Suzuki and Atsushi Hasegawa and Hiroshi Yamaguchi and Kazuo Kashiwabara and Takagi, \{Hideo D.\}",

year = "2006",

month = oct,

doi = "10.1107/S0108270106023596",

language = "English",

volume = "62",

pages = "m461--m463",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "10",

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T1 - Cis-Bis[(3-aminopropyl)dimethylphosphine-κ2N,P] palladium(II) dichloride methanol solvate

AU - Suzuki, Takayoshi

AU - Hasegawa, Atsushi

AU - Yamaguchi, Hiroshi

AU - Kashiwabara, Kazuo

AU - Takagi, Hideo D.

PY - 2006/10

Y1 - 2006/10

N2 - In the title compound, CM-[Pd(C5Hi14NP) 2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P 2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 Å, indicating no obvious interaction.

AB - In the title compound, CM-[Pd(C5Hi14NP) 2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P 2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 Å, indicating no obvious interaction.

UR - https://www.scopus.com/pages/publications/33749485103

UR - https://www.scopus.com/pages/publications/33749485103#tab=citedBy

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DO - 10.1107/S0108270106023596

M3 - Article

AN - SCOPUS:33749485103

SN - 0108-2701

VL - 62

SP - m461-m463

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 10

ER -

Cis-Bis[(3-aminopropyl)dimethylphosphine-κ²N,P] palladium(II) dichloride methanol solvate

Abstract

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