Abstract
N-Cyanomethyl-, N-ethoxycarbonylmethyl- and N-(3-ethoxycarbonylpropyl)-N-methylbenzylammonium N-methylides 6a,b and 22 have been generated by fluoride ion-induced desilylation of the corresponding N-(trimethylsilylmethyl)benzylammonium salts 5a,b and 21. Sommelet-Hauser 7, 23 and Stevens 8, 24 rearrangement products were obtained from 6a and 22, but not from 6b.
| Original language | English |
|---|---|
| Pages (from-to) | 25-28 |
| Number of pages | 4 |
| Journal | Journal of the Chemical Society - Perkin Transactions 1 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 07-01-1997 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Chemistry(all)
Fingerprint Dive into the research topics of 'Generation and reaction of benzylammonium N-methylides with N-cyanomethyl or N-(ethoxycarbonylalkyl) groups'. Together they form a unique fingerprint.
Cite this
Zhang, C., Maeda, Y., Shirai, N., & Sato, Y. (1997). Generation and reaction of benzylammonium N-methylides with N-cyanomethyl or N-(ethoxycarbonylalkyl) groups. Journal of the Chemical Society - Perkin Transactions 1, (1), 25-28. https://doi.org/10.1039/a605337h