Generation and reaction of benzylammonium N-methylides with N-cyanomethyl or N-(ethoxycarbonylalkyl) groups

Chen Zhang, Yasuhiro Maeda, Naohiro Shirai, Yoshiro Sato

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

N-Cyanomethyl-, N-ethoxycarbonylmethyl- and N-(3-ethoxycarbonylpropyl)-N-methylbenzylammonium N-methylides 6a,b and 22 have been generated by fluoride ion-induced desilylation of the corresponding N-(trimethylsilylmethyl)benzylammonium salts 5a,b and 21. Sommelet-Hauser 7, 23 and Stevens 8, 24 rearrangement products were obtained from 6a and 22, but not from 6b.

Original languageEnglish
Pages (from-to)25-28
Number of pages4
JournalJournal of the Chemical Society - Perkin Transactions 1
Issue number1
DOIs
Publication statusPublished - 07-01-1997
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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