TY - JOUR
T1 - Generation and reaction of benzylammonium N-methylides with N-cyanomethyl or N-(ethoxycarbonylalkyl) groups
AU - Zhang, Chen
AU - Maeda, Yasuhiro
AU - Shirai, Naohiro
AU - Sato, Yoshiro
PY - 1997/1/7
Y1 - 1997/1/7
N2 - N-Cyanomethyl-, N-ethoxycarbonylmethyl- and N-(3-ethoxycarbonylpropyl)-N-methylbenzylammonium N-methylides 6a,b and 22 have been generated by fluoride ion-induced desilylation of the corresponding N-(trimethylsilylmethyl)benzylammonium salts 5a,b and 21. Sommelet-Hauser 7, 23 and Stevens 8, 24 rearrangement products were obtained from 6a and 22, but not from 6b.
AB - N-Cyanomethyl-, N-ethoxycarbonylmethyl- and N-(3-ethoxycarbonylpropyl)-N-methylbenzylammonium N-methylides 6a,b and 22 have been generated by fluoride ion-induced desilylation of the corresponding N-(trimethylsilylmethyl)benzylammonium salts 5a,b and 21. Sommelet-Hauser 7, 23 and Stevens 8, 24 rearrangement products were obtained from 6a and 22, but not from 6b.
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U2 - 10.1039/a605337h
DO - 10.1039/a605337h
M3 - Article
AN - SCOPUS:2942687944
SP - 25
EP - 28
JO - Journal of the Chemical Society, Perkin Transactions 1
JF - Journal of the Chemical Society, Perkin Transactions 1
SN - 0300-922X
IS - 1
ER -