Host-guest complexation behavior of resorcinarenes with tetraalkylammonium ions and N-methylpyridinium ions in methanol: The effect of bulky hydrophobic substituents at the extra-annular positions

Osamu Morikawa; Hiroshi Yamaguchi; Yoshiko Katsube; Kazuyuki Abe; Kazuhiro Kobayashi; Hisatoshi Konishi

doi:10.1080/10426500600865152

Host-guest complexation behavior of resorcinarenes with tetraalkylammonium ions and N-methylpyridinium ions in methanol: The effect of bulky hydrophobic substituents at the extra-annular positions

Osamu Morikawa
, Hiroshi Yamaguchi
, Yoshiko Katsube
, Kazuyuki Abe
, Kazuhiro Kobayashi
, Hisatoshi Konishi

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The host-guest interaction of C-methylresorcin[4]arene and its derivative having four tert-butylsulfanylmethyl groups at the extra-annular positions was studied by ¹H NMR spectroscopy in CD₃OD. Based on the association constants (Ka) and the complexation-induced NMR shifts (CIS), it was concluded that the bulky substituents create a deep cavity with a narrow entrance and improve the size and shape selectivity.

Original language	English
Pages (from-to)	2877-2886
Number of pages	10
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	181
Issue number	12
DOIs	https://doi.org/10.1080/10426500600865152
Publication status	Published - 01-12-2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Organic Chemistry
Inorganic Chemistry

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10.1080/10426500600865152

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Morikawa, O., Yamaguchi, H., Katsube, Y., Abe, K., Kobayashi, K., & Konishi, H. (2006). Host-guest complexation behavior of resorcinarenes with tetraalkylammonium ions and N-methylpyridinium ions in methanol: The effect of bulky hydrophobic substituents at the extra-annular positions. Phosphorus, Sulfur and Silicon and the Related Elements, 181(12), 2877-2886. https://doi.org/10.1080/10426500600865152

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title = "Host-guest complexation behavior of resorcinarenes with tetraalkylammonium ions and N-methylpyridinium ions in methanol: The effect of bulky hydrophobic substituents at the extra-annular positions",

abstract = "The host-guest interaction of C-methylresorcin[4]arene and its derivative having four tert-butylsulfanylmethyl groups at the extra-annular positions was studied by 1H NMR spectroscopy in CD3OD. Based on the association constants (Ka) and the complexation-induced NMR shifts (CIS), it was concluded that the bulky substituents create a deep cavity with a narrow entrance and improve the size and shape selectivity.",

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Morikawa, O, Yamaguchi, H, Katsube, Y, Abe, K, Kobayashi, K & Konishi, H 2006, 'Host-guest complexation behavior of resorcinarenes with tetraalkylammonium ions and N-methylpyridinium ions in methanol: The effect of bulky hydrophobic substituents at the extra-annular positions', Phosphorus, Sulfur and Silicon and the Related Elements, vol. 181, no. 12, pp. 2877-2886. https://doi.org/10.1080/10426500600865152

Host-guest complexation behavior of resorcinarenes with tetraalkylammonium ions and N-methylpyridinium ions in methanol: The effect of bulky hydrophobic substituents at the extra-annular positions. / Morikawa, Osamu; Yamaguchi, Hiroshi; Katsube, Yoshiko et al.
In: Phosphorus, Sulfur and Silicon and the Related Elements, Vol. 181, No. 12, 01.12.2006, p. 2877-2886.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Host-guest complexation behavior of resorcinarenes with tetraalkylammonium ions and N-methylpyridinium ions in methanol

T2 - The effect of bulky hydrophobic substituents at the extra-annular positions

AU - Morikawa, Osamu

AU - Yamaguchi, Hiroshi

AU - Katsube, Yoshiko

AU - Abe, Kazuyuki

AU - Kobayashi, Kazuhiro

AU - Konishi, Hisatoshi

PY - 2006/12/1

Y1 - 2006/12/1

N2 - The host-guest interaction of C-methylresorcin[4]arene and its derivative having four tert-butylsulfanylmethyl groups at the extra-annular positions was studied by 1H NMR spectroscopy in CD3OD. Based on the association constants (Ka) and the complexation-induced NMR shifts (CIS), it was concluded that the bulky substituents create a deep cavity with a narrow entrance and improve the size and shape selectivity.

AB - The host-guest interaction of C-methylresorcin[4]arene and its derivative having four tert-butylsulfanylmethyl groups at the extra-annular positions was studied by 1H NMR spectroscopy in CD3OD. Based on the association constants (Ka) and the complexation-induced NMR shifts (CIS), it was concluded that the bulky substituents create a deep cavity with a narrow entrance and improve the size and shape selectivity.

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DO - 10.1080/10426500600865152

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JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

IS - 12

ER -

Morikawa O, Yamaguchi H, Katsube Y, Abe K, Kobayashi K, Konishi H. Host-guest complexation behavior of resorcinarenes with tetraalkylammonium ions and N-methylpyridinium ions in methanol: The effect of bulky hydrophobic substituents at the extra-annular positions. Phosphorus, Sulfur and Silicon and the Related Elements. 2006 Dec 1;181(12):2877-2886. doi: 10.1080/10426500600865152

Host-guest complexation behavior of resorcinarenes with tetraalkylammonium ions and N-methylpyridinium ions in methanol: The effect of bulky hydrophobic substituents at the extra-annular positions

Abstract

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