Cis-Bis[(3-aminopropyl)dimethylphosphine-κ2N,P] palladium(II) dichloride methanol solvate

Takayoshi Suzuki; Atsushi Hasegawa; Hiroshi Yamaguchi; Kazuo Kashiwabara; Hideo D. Takagi

doi:10.1107/S0108270106023596

Cis-Bis[(3-aminopropyl)dimethylphosphine-κ²N,P] palladium(II) dichloride methanol solvate

Takayoshi Suzuki
, Atsushi Hasegawa
, Hiroshi Yamaguchi
, Kazuo Kashiwabara
, Hideo D. Takagi

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

抄録

In the title compound, CM-[Pd(C₅Hi₁₄NP) ₂]Cl₂·CH₄O, the coordination geometry around the Pd^II center is distorted square planar, with a cis-P ₂N₂ configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (C_s)-chair₂ conformer. The distances between the Pd^II center and the Cl^- anions are greater than 4.5 Å, indicating no obvious interaction.

本文言語	英語
ページ（範囲）	m461-m463
ジャーナル	Acta Crystallographica Section C: Crystal Structure Communications
巻	62
号	10
DOI	https://doi.org/10.1107/S0108270106023596
出版ステータス	出版済み - 10-2006
外部発表	はい

All Science Journal Classification (ASJC) codes

生化学、遺伝学、分子生物学一般

文献へのアクセス

10.1107/S0108270106023596

他のファイルとリンク

引用スタイル

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title = "Cis-Bis[(3-aminopropyl)dimethylphosphine-κ2N,P] palladium(II) dichloride methanol solvate",

abstract = "In the title compound, CM-[Pd(C5Hi14NP) 2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P 2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 {\AA}, indicating no obvious interaction.",

author = "Takayoshi Suzuki and Atsushi Hasegawa and Hiroshi Yamaguchi and Kazuo Kashiwabara and Takagi, \{Hideo D.\}",

year = "2006",

month = oct,

doi = "10.1107/S0108270106023596",

language = "English",

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pages = "m461--m463",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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publisher = "International Union of Crystallography",

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T1 - Cis-Bis[(3-aminopropyl)dimethylphosphine-κ2N,P] palladium(II) dichloride methanol solvate

AU - Suzuki, Takayoshi

AU - Hasegawa, Atsushi

AU - Yamaguchi, Hiroshi

AU - Kashiwabara, Kazuo

AU - Takagi, Hideo D.

PY - 2006/10

Y1 - 2006/10

N2 - In the title compound, CM-[Pd(C5Hi14NP) 2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P 2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 Å, indicating no obvious interaction.

AB - In the title compound, CM-[Pd(C5Hi14NP) 2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P 2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 Å, indicating no obvious interaction.

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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